| 101. | Anthony Brewer | OF | FLA | 17 | 8/2/1982 | 6-0 | 165 | R-R | A | | Simeon High School (Chicago,IL) | 18 |
| 102. | Jason Miller | P | MIN | 17 | 7/20/1982 | 6-1 | 202 | L-L | MLB | 2007-2007 | Sarasota High School (Sarasota,FL) | 36 |
| 106. | Zach Miner | P | ATL | 18 | 3/12/1982 | 6-3 | 190 | R-R | MLB | 2006-2008 | Palm Beach Gardens High School (Palm Beach Gardens,FL) | 3 |
| 109. | Mewelde Moore | OF | SD | 17 | 7/24/1982 | 6-0 | 190 | R-R | Rookie | | Belaire High School (Baton Rouge,LA) | 4 |
| 111. | Eric Henderson | P | MIL | 20 | 9/5/1979 | 6-4 | 210 | L-L | A+ | | University of North Carolina | 107 |
| 112. | Alvin Jones | P | CHW | 18 | 5/21/1982 | 6-4 | 210 | R-R | Rookie | | Seguin High School (Seguin,TX) | 3 |
| 113. | Yadier Molina | C | STL | 17 | 7/13/1982 | 5-11 | 187 | R-R | MLB | 2004-2008 | Maestro Ladi High School (Vega Alta,PR) | 2 |
| 116. | Sam Hays | P | SEA | 18 | 10/7/1981 | 6-5 | 210 | L-L | A- | | Waco High School (Waco,TX) | 4 |
| 118. | Raul Tablado | IF | TOR | 18 | 3/3/1982 | 6-2 | 175 | R-R | AA | | Southridge High School (Miami,FL) | 4 |
| 121. | Ryan Hannaman | P | SF | 18 | 8/28/1981 | 6-3 | 190 | L-L | A+ | | Murphy High School (Mobile,AL) | 5 |
| 122. | Brandon Mims | P | BOS | 18 | 12/2/1981 | 6-2 | 180 | L-L | A- | | Prattville High School (Prattville,AL) | 2 |
| 123. | Marc Kaiser | P | CIN | 18 | 5/7/1982 | 6-2 | 205 | R-R | AAA | | Reno High School (Reno,NV) | 2 |
| 124. | Laynce Nix | OF | TEX | 19 | 10/30/1980 | 6-0 | 190 | L-L | MLB | 2003-2007 | Midland High School (Midland,TX) | 3 |
| 127. | Eric Keefner | 1B | HOU | 18 | 12/8/1981 | 6-3 | 220 | R-R | Ind | | De La Salle High School (Chicago,IL) | 2 |
| 128. | Matt Smith | P | NYY | 21 | 6/15/1979 | 6-5 | 225 | L-L | MLB | 2006-2007 | Oklahoma State University | 148 |
| 129. | Josh Kroeger | OF | ARI | 17 | 8/31/1982 | 6-2 | 195 | L-L | MLB | 2004-2004 | Scripps Ranch High School (San Diego,CA) | 2 |